The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Silicon compounds / Si(CH3)4 / SouzaSrivastava(1994)_298K_12.4-206.6nm

DATAFILE: Si(CH3)4_SouzaSrivastava(1994)_298K_12.4-206.6nm.txt
NAME: tetramethylsilane
FORMULA: Si(CH3)4
AUTHOR(YEAR): SouzaSrivastava(1994)
T: 298K
λ: 12.4-206.6nm
BIBLIOGRAPHY: A.C.A. Souza and S.K. Srivastava, "Photoabsorption cross sections of Ar, N2 and Si(CH3)4 from electron energy loss spectroscopy", J. Braz. Chem. Soc. 5, 59-65 (1994); DOI: 10.5935/0103-5053.19940010
COMMENTS: The electron energy loss (EEL) spectrum of Si(CH3)4 measured in a crossed electron beam-molecular beam collision geometry has been converted to the photoabsorption spectrum, and the relative absorption cross sections have then been normalized to the absorption cross section at 65 nm measured by

K. Kameta, M. Ukai, T. Numazawa, N. Terezawa, Y. Chikahiro, N. Kouchi, and Y. Hatano, "Photoabsorption, photoionization, and neutral-dissociation cross sections of SiF4, SiCl4, and Si(CH3)4 in the extreme ultraviolet", J. Chem. Phys. 99, 2487-2494 (1993); DOI: 10.1063/1.465211

Data for photon energies from 6 to 100 eV (Table 3) have been converted to absorption cross sections vs. wavelength

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